The most famous real numbers that
are not rational are the numbers pi and e. However
there are many interesting constants in mathematics,
as described at the following site:
http://algo.inria.fr/bsolve/
This site answers some questions
about numeration systems:
http://www.math.toronto.edu/mathnet/answers/numbersystems.html
The number
0, the additive identity, is the subject of many
web sites:
http://www.math.toronto.edu/mathnet/plain/questionCorner/zeroorigin.html
http://mathforum.org/dr/math/problems/purpose_zero.html